Ann Hathaway and husband New York - Arabstoday Ann Hathaway and Adam Shulman tied the knot in a private estate in Big Sur, CA. The couple said “I do” in front of over 100 family and friends in a private ceremony that was followed by a reception.   The lovely actress wore an off-the-shoulder gown designed by Valentino with a headpiece and veil, while Adam wore a traditional tuxedo. Speaking recently, Valentino Garavani confirmed he had designed the gown that would be worn by the “Les Miserables” beauty. The décor of the big day was reportedly inspired by nature and featured lots of branches at both the ceremony and reception.